CONF 03500 BenzeneExercises¬ HalideExercises¬ TEXT HEAD Halides¬ LINE¬ TITL Halides Introduction¬ 00 PLAN¬ IGNO The functional group of alkyl halides is a carbon-halogen bond, the common halogens being fluorine, chlorine, bromine and iodine. With the exception of iodine, these halogens have electronegativities significantly greater than carbon. Consequently, this functional group is polarized so that the carbon is electrophilic and the halogen is nucleophilic.¬ CIMG 020 080 cxpolary¬³ TRGT TEXT TITL Preperation¬ 00 LINE¬³ TEXT TITL Preparation of Alkyle Halides in Laboratory¬ 00 LINE¬³ TEXT IGNO Following list some of the methods to derive halides from other organic compounds¬LINE¬³ TEXT LINE¬³ RACT CMPD 030 000 ethane¬ PLUS 050 025 CIMG 000 000 cl2¬ ARRW 050 050 025 hmu¬ NULL¬ CMPD 000 040 1chloroethane¬³ TEXT LINE¬³ RACT CMPD 040 000 ethene¬ PLUS 050 025 CIMG 000 000 hCl¬ ARRW 050 050 025 NULL¬ NULL¬ CMPD 000 060 1chloroethane¬³ TEXT LINE¬³ TRGT TEXT TITL Reactions¬ 00 LINE¬³ TRGT TEXT TITL Removal Reactions¬ 00 LINE¬³ RACT CMPD 070 000 1chloroethane¬ PLUS 050 025 CIMG 000 000 KOH¬ ARRW 050 140 140 Alcoholic¬ NULL¬ CMPD 000 040 ethene¬³ TEXT LINE¬³ RACT CMPD 050 000 1-chloropropane¬ PLUS 050 025 CIMG 000 000 KOH¬ ARRW 050 140 140 Alcoholic¬ NULL¬ CMPD 000 080 prop1ene¬³ TRGT TEXT TITL Substitutional Reactions¬ 00 LINE¬³ TRGT TEXT TITL To form Alcohol¬ 00 LINE¬ IGNO Alkyle halides react with aquatic KOH and form corresponding Alcohol ¬LINE¬³ RACT CMPD 050 000 1chloroethane¬ PLUS 050 025 CIMG 000 000 koh¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 050 ethanole¬³ TEXT LINE¬³ RACT CMPD 050 000 1-chloropropane¬ PLUS 050 025 CIMG 000 000 koh¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 070 propan-1-ole¬³ TRGT TEXT TITL To form Nitrile¬ 00 LINE¬ IGNO Alkyle halides react with aquatic KCN and form nitrile the same way it reacts with KOH to form the Alcohol ¬LINE¬³ RACT CMPD 050 000 chloromethane¬ PLUS 050 025 CIMG 000 000 kCn¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 050 CH3CN¬³ TEXT LINE¬³ RACT CMPD 050 000 1-chloropropane¬ PLUS 050 025 CIMG 000 000 kCn¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 070 CH3CH2CH2CN¬³ TRGT TEXT TITL To form Amiene¬ 00 LINE¬ IGNO Alkyle halides forms amine reacting with Ammonia. ¬LINE¬³ RACT CMPD 050 000 1chloroethane¬ PLUS 050 025 CIMG 000 000 NH3¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 050 ethanamine¬³ TEXT LINE¬³ RACT CMPD 050 000 1-chloropropane¬ PLUS 050 025 CIMG 000 000 kCn¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 050 propan-1-amine¬³ ENDP