CONF 07500 HalideExercises¬ AlcoholExercises¬ TEXT HEAD Alcohol¬ LINE¬ TITL Alcohol Introduction¬ 00 PLAN¬ IGNO Alcohols are an extremely important class of organic compounds that contain the ` hydroxyl (-OH) group. Alcohols are some of the most common and useful compounds in nature and industry. Alcohols can be synthesized by a host of different methods, and are easily converted into other functional groups. For this reason they are often used as intermediates in a larger scale synthesis.¬ CIMG 020 120 AlcoholClassification¬³ TRGT TEXT TITL Preperation¬ 00 LINE¬³ TEXT TITL Preparation of Alcohol in Laboratory¬ 00 LINE¬³ TEXT IGNO Following list some of the methods to derive Alcohol from other organic compounds¬LINE¬³ RACT CMPD 050 000 1chloroethane¬ PLUS 050 025 CIMG 000 000 koh¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 050 ethanole¬³ TEXT LINE¬³ RACT CMPD 050 000 1-chloropropane¬ PLUS 050 025 CIMG 000 000 koh¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 070 propan-1-ole¬³ TRGT TEXT TITL Reactions¬ 00 LINE¬³ TRGT TEXT TITL Removal Reactions¬ 00 LINE¬³ RACT CMPD 070 000 ethanole¬ PLUS 050 025 CIMG 000 000 Al2O3¬ ARRW 050 140 140 NULL¬ Traingle¬ CMPD 000 060 ethene¬³ TEXT LINE¬³ RACT CMPD 050 000 propan-2-ole¬ PLUS 050 025 CIMG 000 000 Al2O3¬ ARRW 050 140 140 NULL¬ Traingle¬ CMPD 000 100 prop1ene¬³ TEXT LINE¬³ RACT CMPD 050 000 2-methylpropan-2-ole¬ PLUS 050 025 CIMG 000 000 Al2O3¬ ARRW 050 140 140 NULL¬ Traingle¬ CMPD 000 140 2-methylprop-1-ene¬³ TRGT TEXT TITL Substitutional Reactions¬ 00 LINE¬³ TRGT TEXT TITL Reaction with Sodium¬ 00 LINE¬ IGNO Alcohol reacts with Sodium and form it Alcoholate together with Hydrogen. Alcoholic compounds can be identified from emits of hydrogen.¬LINE¬³ RACT CMPD 050 000 ethanole¬ PLUS 050 025 CIMG 000 000 Na¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 000 sodium ethoxide¬ PLUS 050 025 CIMG 000 060 H2¬³ TEXT LINE¬³ RACT CMPD 050 000 propan-2-ole¬ PLUS 050 025 CIMG 000 000 koh¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 000 sodium propoxide¬ PLUS 050 025 CIMG 000 060 H2¬³ TEXT LINE¬³ RACT CMPD 030 000 phenylmethanole¬ PLUS 050 025 CIMG 000 000 koh¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 000 CH2-ONa¬ PLUS 050 025 CIMG 000 060 H2¬³ TRGT TEXT TITL Reaction with Carboxylic acid¬ 00 TITL and acid Chloride¬ 40 LINE¬ IGNO Alcohol reacts with Carboxylic acid and acid chloride and form an ester ¬LINE¬³ RACT CMPD 050 000 ethanole¬ PLUS 050 025 CMPD 000 000 carboxylic acid¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 000 ester1¬ PLUS 050 025 CIMG 000 060 H2o¬³ TEXT LINE¬³ RACT CMPD 050 000 ethanole¬ PLUS 050 025 CMPD 000 000 acid chloride¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 000 ester1¬ PLUS 050 025 CIMG 000 060 Hcl¬³ TEXT LINE¬³ RACT CMPD 050 000 propan-2-ole¬ PLUS 050 025 CMPD 000 000 carboxylic acid¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 000 ester2¬ PLUS 050 025 CIMG 000 080 H2o¬³ TEXT LINE¬³ RACT CMPD 050 000 propan-2-ole¬ PLUS 050 025 CMPD 000 000 acid chloride¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 000 ester2¬ PLUS 050 025 CIMG 000 100 Hcl¬³ TRGT TEXT TITL Reaction With Potassium Chloride¬ 00 LINE¬ IGNO Alcohol reacts with either ¬ CIMG 000 000 pcl3¬IGNO or ¬ CIMG 000 000 pcl5¬IGNO and forms corresponding Alkyle chloride.¬ LINE¬³ RACT CMPD 050 000 ethanole¬ PLUS 050 025 CIMG 000 000 PCL3¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 050 1chloroethane¬³ TEXT LINE¬³ RACT CMPD 050 000 propan2ole¬ PLUS 050 025 CIMG 000 000 PCL5¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 050 2chloropropane¬³ TRGT TEXT TITL Reaction With Halogen¬ 00 LINE¬ IGNO Alcohol reacts with Halogen except HCl in the following manner¬ LINE¬³ RACT CMPD 050 000 ethanole¬ PLUS 050 025 CIMG 000 000 Hi¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 050 1iodoethane¬³ TEXT LINE¬³ RACT CMPD 050 000 propan2ole¬ PLUS 050 025 CIMG 000 000 Hbr¬ ARRW 050 140 140 NULL¬ NULL¬ CMPD 000 050 2bromopropane¬³ TEXT LINE¬³ TEXT IGNO Alkyle Cloride can be derived using Non Aqueous Zinc Cloride and conc. HCl . ¬ LINE¬³ RACT CMPD 050 000 ethanole¬ PLUS 050 025 CIMG 000 000 Hcl¬ ARRW 050 140 140 ZnCl¬ NULL¬ CMPD 000 050 1chloroethane¬³ TEXT LINE¬³ RACT CMPD 050 000 propan2ole¬ PLUS 050 025 CIMG 000 000 Hcl¬ ARRW 050 140 140 ZnCl¬ NULL¬ CMPD 000 050 2chloropropane¬³ TRGT TEXT TITL Oxidization¬ 00 LINE¬ IGNO Alcohol oxidize and forms either keton aldehyde or Carboxilic acid. The reuslt depends on the oxidization level and shape of the Compound. In fact Tertiary Alcohol won't oxidize becasue no hydrogen is attached to the carbon with the OH group.¬LINE¬³ RACT CMPD 050 000 methanole¬ PLUS 050 025 CIMG 000 000 KMno4¬ ARRW 050 140 140 acidic¬ NULL¬ CIMG 000 050 co2¬³ TEXT LINE¬³ RACT CMPD 050 000 ethanole¬ PLUS 050 025 CIMG 000 000 kmno4¬ ARRW 050 140 140 acidic¬ NULL¬ CMPD 000 050 ethanoic acid¬³ TEXT LINE¬³ RACT CMPD 050 000 propan2ole¬ PLUS 050 025 CIMG 000 000 kmno4¬ ARRW 050 140 140 acidic¬ NULL¬ CMPD 000 050 propan-2-one¬³ TEXT LINE¬³ ENDP